3D-printing applied sciences for polymeric formulations are experiencing an enormous improvement because of the advanced and particular geometries that may be lined using additive manufacturing. Nevertheless, to make sure sustainable development, it’s important to switch the presently used fossil-based resins with new bio-sourced alternate options. On this research, tunable bis-allylated compounds have been effectively synthesized from cellulose-derived levoglucosenone through a chemo-enzymatic pathway whom greenness has been assessed by E-factor and Eco-Scale. Subsequently, photocuring was employed as an eco-friendly course of to polymerize these compounds with a trifunctional thiol utilizing thiol-ene click on chemistry. Actual-time strategies resembling FT-IR, photo-DSC, and photo-rheology have been employed to extensively characterize the UV-process. The ensuing thermosets have been additionally subjected to an intensive evaluation, protecting their thermal-mechanical properties and degradation. Owing to the distinctive reactivity of this thiol-ene system, 3-D printed supplies have been achieved with outstanding precision.